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Shells and valency

Arrange electrons in shells and find an element's valency.

How electrons fill the shells (the Bohr–Bury rules, from two scientists, Bohr and Bury):

  • Shell n holds at most 2n² electrons: K (n = 1) holds 2, L (n = 2) holds 8, M (n = 3) holds 18.
  • The outermost shell holds at most 8.
  • Shells fill in order, K then L then M: the next one starts only when the one before is full.

The way electrons are arranged in shells is the electronic configuration:

  • hydrogen 1; helium 2;
  • carbon 2, 4;
  • sodium 2, 8, 1;
  • argon 2, 8, 8.

The outermost shell is the valence shell, and its electrons are valence electrons. Eight electrons there make an octet. Atoms with a full octet (or helium, with its full K shell of 2) are stable: they sit quietly and hardly react with anything.

Combining capacity. Count how many hydrogen or chlorine atoms one atom joins with:

  • in H₂O, oxygen joins 2 H atoms, so its capacity is 2;
  • in NH₃, nitrogen joins 3;
  • in MgCl₂, magnesium joins 2 Cl atoms.

Valency is the number of electrons an atom loses, gains or shares to get a full octet. Think of it like hunger: if you have only one roti and need four, it's easier to give that one away. Atoms do the same:

  • Fewer than 4 valence electrons: it gives them away. Sodium (2, 8, 1) loses 1, so its valency is 1.
  • More than 4: it takes more. Oxygen (2, 6) gains 2, so its valency is 2.
  • Exactly 4: it shares. Carbon (2, 4) shares 4, so its valency is 4.

Valencies of the first 18 elements:

Elements 1 to 6Elements 7 to 12Elements 13 to 18
H 1N 3Al 3
He 0O 2Si 4
Li 1F 1P 3
Be 2Ne 0S 2
B 3Na 1Cl 1
C 4Mg 2Ar 0
Each shell holds at most 2n² electrons and the outermost at most 8. Valency is how many electrons an atom gives, takes or shares to fill it.
Electronic configurations of carbon, sodium and argon.

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