Journey Inside the Atom
Shells and valency
Arrange electrons in shells and find an element's valency.
How electrons fill the shells (the Bohr–Bury rules, from two scientists, Bohr and Bury):
- Shell n holds at most 2n² electrons: K (n = 1) holds 2, L (n = 2) holds 8, M (n = 3) holds 18.
- The outermost shell holds at most 8.
- Shells fill in order, K then L then M: the next one starts only when the one before is full.
The way electrons are arranged in shells is the electronic configuration:
- hydrogen 1; helium 2;
- carbon 2, 4;
- sodium 2, 8, 1;
- argon 2, 8, 8.
The outermost shell is the valence shell, and its electrons are valence electrons. Eight electrons there make an octet. Atoms with a full octet (or helium, with its full K shell of 2) are stable: they sit quietly and hardly react with anything.
Combining capacity. Count how many hydrogen or chlorine atoms one atom joins with:
- in H₂O, oxygen joins 2 H atoms, so its capacity is 2;
- in NH₃, nitrogen joins 3;
- in MgCl₂, magnesium joins 2 Cl atoms.
Valency is the number of electrons an atom loses, gains or shares to get a full octet. Think of it like hunger: if you have only one roti and need four, it's easier to give that one away. Atoms do the same:
- Fewer than 4 valence electrons: it gives them away. Sodium (2, 8, 1) loses 1, so its valency is 1.
- More than 4: it takes more. Oxygen (2, 6) gains 2, so its valency is 2.
- Exactly 4: it shares. Carbon (2, 4) shares 4, so its valency is 4.
Valencies of the first 18 elements:
| Elements 1 to 6 | Elements 7 to 12 | Elements 13 to 18 |
|---|---|---|
| H 1 | N 3 | Al 3 |
| He 0 | O 2 | Si 4 |
| Li 1 | F 1 | P 3 |
| Be 2 | Ne 0 | S 2 |
| B 3 | Na 1 | Cl 1 |
| C 4 | Mg 2 | Ar 0 |
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