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Carbon and its Compounds

Covalent bonding

Learn how atoms share electrons to form covalent bonds.

Your food, clothes, medicines, books, and your own body are mostly made of carbon compounds. So how does carbon bond?

Carbon has electrons 2, 4. To get a full outer shell, could it lose 4 electrons, or gain 4?

  • Lose 4 (C⁴⁺): far too much energy is needed to pull away four electrons.
  • Gain 4 (C⁴⁻): six protons would have to hold on to ten electrons. That's like one teacher trying to control a huge class: it can't hold them.

Neither works. So carbon does something else: it shares.

A shared pair of electrons between two atoms is a covalent bond. Each atom counts the shared electrons as its own, so both reach a full shell.

Shared pairsBondExample
onesingle (–)H–H, Cl–Cl, the C–H bonds in methane CH₄
twodouble (=)O=O
threetriple (≡)N≡N

Inside a molecule the bonds are strong, but the pull between molecules is weak. So covalent compounds usually have low melting and boiling points: methane boils at 111 K, far below room temperature. They make no ions, so they don't conduct electricity.

Pure carbon comes in different forms, called allotropes. How do we know they are all carbon? Each one burns to give only carbon dioxide.

AllotropeStructureProperty
Diamondeach carbon joined to four others in a rigid 3-D framethe hardest natural substance
Graphiteflat layers of hexagons that slide over each othersmooth, slippery, conducts electricity
Fullerene (C-60)60 carbons arranged like a footballa newer form; named after the architect Buckminster Fuller
Carbon can neither lose nor gain four electrons easily, so it shares them: a shared pair is a covalent bond.
Each shared pair of electrons is one covalent bond.

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